Research

Our research focuses on the organoelement chemistry of the p-block elements in particular. Based on fundamental molecular features derived from specific bonding situations, unique properties such as s- and p-conjugation can be achieved. In this respect controlling the stereochemistry of stereogenic group 15 centers is part of our investigations, be it for fundamental questions of chirality or the stereochemical alignment of multiple stereogenic centers. In our research we are aiming at the assembly of molecular materials with a special focus on smart inorganic polymers as part of a European research initiative (SIPs). Key publications on specific topics see below.

Hybrid materials and supramolecular architectures

  • Molecular materials and surface chemistry

R. Pietschnig, "Polymers with pendant ferrocenes" Chem. Soc. Rev. 2016, 45, 5216-5231.


R. Pietschnig, S. Spirk, "The Chemistry of Organo Silanetriols" Coord. Chem. Rev. 2016, 87-106.

M. Reiner, R. Pietschnig, C. Ostermaier, "Tracking the Effect of Ad-Atom Electronegativity on Systematically Modified AlGaN/GaN Schottky Interfaces" Appl. Mater. Interfaces, 2015, 7(41), 23124-23131.

N. Hurkes, H. Ehmann, M. List, S. Spirk, M. Bussiek, F. Belaj, R. Pietschnig, "Silanol Based Surfactants - Synthetic Access and Properties of an Innovative Class of Environmentally Benign Detergents" Chem. Eur. J. 2014, 20, 9330-9335.

S. Spirk, H. Ehmann, M. Reischl, R. Kargl, N. Hurkes, M. Wu, J. Novak, R. Resel., R. Pietschnig, V. Ribitsch, "Surface Modifications Using a Water Stable Silanetriol in Neutral Aqueous Media ", Appl. Mat. Interf. 2010, 2, 2956.

Fundamental organoelement chemistry

  • Unique bonding situation and electronic properties

  1. S. Borucki, Z. Kelemen, M. Maurer, C. Bruhn, L. Nyulászi, R. Pietschnig, "Stereochemical alignment in triphospha-[3]ferrocenophanesChem. Eur. J. 2017, accepted. link

  2. M. Blunder, N. Hurkes, M. List, S. Spirk, R. Pietschnig, "Silanetriols as in vitro AChE Inhibitors", Bioorg. Med. Chem. Lett., 2011, 21, 363.

  3. S. Spirk, F. Belaj, J. H. Albering, R. Pietschnig, "Formation of a Silylated 1-Silaallene via an Intermediate 1-Chloro-1-Silaallene", Organometallics., 2010, 29, 2981.

  4. C. Moser, F. Belaj, R. Pietschnig, "Diphospha[2]ferrocenophane and 1,4-dihydrotetraphosphane - Stereoselective Formation via hydrolytic P-P bond formation”, Chem. Eur. J., 2009, 15, 12589.

  5. R. Pietschnig, D. R. Powell and R. West, "Reduction of Terphenyltrifluorosilanes: C-C Insertion Products and Possible Formation of a Disilyne", Organometallics, 2000, 19, 2724.

Sustainable Chemistry

  • Energy storage materials and catalytic C-H Activation

  1. T. Brünig, M. Maurer, R. Pietschnig, "Sorbent Properties of Halide free Ionic liquids for Water and CO2 Perfusion" ACS Sustainable Chem. Eng., 2017, accepted. link

  2. T. Brünig, K. Krekić, C. Bruhn, R. Pietschnig, "Calorimetric studies and structural aspects of Ionic Liquids in designing sorption materials for thermal energy storage" Chem. Eur. J., 2016, 22, 16200-16212. link

  3. E. F. Aboelfetoh, R. Pietschnig, "Preparation, Characterization and Catalytic Activity of MgO/SiO2 supported Vanadium Oxide Based Catalysts" Catal. Lett. 2014, 144, 97-103.

  4. E. Fahmy Aboelfetoh, R. Pietschnig, "Preparation and Catalytic Performance of Al2O3, TiO2 and SiO2 Supported Vanadium Based-Catalysts for C-H Activation", Catal. Lett., 2009, 127, 83.